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纸质出版日期:1994,
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[1]丁世家,袁太先.铜-嘌呤配位吸附波研究[J].重庆医科大学学报,1994(02):133-135.
THE ADSORPTIVE-COMPLEX WAVE FO Cu(Ⅱ)-Purine[J]. Journal of Chongqing Medical University, 1994,(2).
[1]丁世家,袁太先.铜-嘌呤配位吸附波研究[J].重庆医科大学学报,1994(02):133-135. DOI:
THE ADSORPTIVE-COMPLEX WAVE FO Cu(Ⅱ)-Purine[J]. Journal of Chongqing Medical University, 1994,(2). DOI:
本文提出了Cu(Ⅱ)──嘌呤配位吸附波。在pH为6.90的B·R缓冲溶液中,该波的峰电位为-0.240(V)(vs·SCE),对极谱波的电流,电位性质和电极反应机理进行了研究,利用该波的一阶导数值可测定铜离子浓度,检测下限为9.0×10 ̄(-8)mol·dm ̄(-3)。
n this paper
the adsorptive-complex wave of Cu(Ⅱ)─purine is proposed
In the supportingelectrolyte of BR buffer solution at pH= 6.90
the peak potential of the wave is about-0.24OV(vs.SCE).The behaviour of current-potential curve and the mechanism of electrodereaction were studied
several electrochemical parameters were determined
The concentration ofCopper(Ⅱ)can be measured by using the first deravative adsorptive-complex ipp
the detectionlimitation is 9
00×10 ̄(-8)mol.dm ̄(-3)。
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